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    How to choose the right polypropylene grade for your application Ⅲ

    2022-01-21 15:40:37  News


    How to choose the right polypropylene grade for your application 

    In this blog post, we will discuss the mechanical properties of polypropylene. All human civilizations are built on an understanding of natureLikewise, a good understanding of the mechanical properties of polypropylene is necessary to select the correct polypropylene grade for your product.


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    What is the mechanical properties of polypropylene?

    Polypropylene product design engineers are most interested in stiffness, strength, and impact resistance. The stiffness of polypropylene is measured by the flexural modulus, which is determined in a flexural test, and the impact strength is measured by a number of different impact tests. By far the most popular is the Izod impact test at normal ambient and sub-ambient temperatures.

    These mechanical properties are mostly used to predict the properties of molded products.The strength of polypropylene is usually given by the yield point rather than the breaking strength, but breaking strength usually refers to the strength of fibers and films under tensile stress.


    How to get the mechanical data of polypropylene?

    In order to understand the use and comparison of mechanical property data, it is important to remember that mechanical property testing is not a measurement of polypropylene resin itself but a sample of the resin product. Mechanical property data is derived from product stewardship and the mechanical property testing process.

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    There are many variables that affect the mechanical properties of polypropylene, so when a person asks about the mechanical properties of polypropylene, the first answer is what test, what specimen, and in what environment. Subsequent responses include the exact sample type, age of the sample, specimen condition, test speed, test temperature, data acquisition process, and data collection method. Usually the mechanical properties of polypropylene are tested in accordance with ASTM or ISO regulations.


     How to select the mechanical properties of polypropylene?

    From the perspective of the production process of polypropylene, the mechanical properties of polypropylene can be graded by molecular weight(MW), molecular weight distribution(MWD), ethylene content (random copolymer), content and composition of the modified phase (block copolymer), and the general trend is as follows

    Characteristic

    Homopolymer

    Random copolymer

    Block

    Contact clarity

    YES

    YES

    NO

    See through clarity

    NO

    YES

    NO

    Cold temperature impact

    NO

    lIMITED

    YES

    Extreme Elevated Temperature

    YES

    NO

    LIMITED

     

    Homopolymers

    Property

    Tensile strength

    Stiffness

    Impact

    Resistance

    Heat Distortion

    Hardness

    Increasing MFR

    +++

    +++

    +++

    +++

     

    Narrowing MWD

    +++

     


    Random Copolymers

    Property

    Clarity

    Tensile strength

    Stiffness

    Impact

    Resistance

    Heat Distortion

    Hardness

    Increasing MFR

    NME

    +++

    +++

    +++

    +++

     

     

    Narrowing MWD

    +++

     

    Increasing Ethylene Content

     

    +++

    +++

     

    Block Copolymer

    Property

    Tensile strength

    Stiffness

    Impact

    Resistance

    Heat Distortion

    Hardness

    Bruise Resistance

    Increasing MFR

    +++

    +++

    +++

    +++

    NME

    Narrowing MWD

    +++

    NME

    Increasing Modifier Content

    +++

     

     

    In conclusion, it is easy to see that when two or more control variables are changed at the same time, co-observation is very common. A very important point that we must understand when selecting polypropylene grades based on their mechanical properties is that a change in one property will cause changes in many other properties, and most of them are negative changes. For instance, The flexural modulus or stiffness increases with increasing crystallinity, but this depends on the type of crystal morphology. Thus, stiffness generally decreases with decreasing crystallinity or, in random copolymers, crystallinity decreases with increasing ethylene content.

     

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    According to this feature of polypropylene, we should give priority to the application requirements of the product when selecting polypropylene grades, and then determine the priority of product data.

    Again, due to the diversity of test methods, sample preparation, data acquisition techniques, data acquisition processes, etc., caution must be exercised when comparing performance data obtained from different suppliers.

     

    Dema commits to create value for our clients, provide solutions of polymer raw materials, like PP, PE, PVC, PET, ABS and FIBC bags, and help you occupied a competitive position in your market. You are welcome to contact us at any time, we will serve you wholeheartedly.


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